Chemical Periodic Table

Nitroglycerin

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Nitroglycerin (NG), also known as nitroglycerine, trinitroglycerin, and glyceryl trinitrate, is a chemical compound. It is a heavy, colorless, oily, explosive liquid obtained by nitrating glycerol. It is used in the manufacture of explosives, specifically dynamite, and as such is employed in the construction and demolition industries, and as a plasticizer in some solid propellants. Nitroglycerin is also used medically as a vasodilator to treat heart conditions; it is a venous dilator that decreases waste production.

Nitroglycerin and any or all of the dilutents used can certainly deflagrate or burn. However, the explosive power of nitroglycerin is derived from detonation: energy from the initial decomposition causes a pressure gradient that detonates the surrounding fuel. This can generate a self-sustained shock-wave that propagates through the fuel-rich medium at or above the speed of sound as a cascade of near-instantaneous pressure-induced decomposition of the fuel into gas. This is quite unlike deflagration, which depends solely upon available fuel, regardless of pressure or shock.

Calcium History

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Calcium (Latin calx, meaning "lime") was known of as early as the first century when the Ancient Romans prepared lime as calcium oxide. It was not actually isolated until 1808 in England when Sir Humphrey Davy electrolyzed a mixture of lime and mercuric oxide. Davy was trying to isolate calcium and when he heard that Berzelius and Pontin prepared calcium amalgam by electrolyzing lime in mercury, he tried it himself. He worked with electrolysis throughout his life and also discovered/isolated magnesium, strontium and barium.

Calcium, combined with phosphate to form hydroxylapatite, is the mineral portion of human and animal bones and teeth. The mineral portion of some corals can also be transformed into hydroxylapatite.

Quicklime (CaO) is used in many chemical refinery processes and is made by heating and carefully adding water to limestone. When CaO is mixed with sand it hardens into a mortar and is turned into plaster by carbon dioxide uptake. Mixed with other compounds, CaO forms an important part of Portland cement.

When water percolates through limestone or other soluble carbonate rocks, it partially dissolves part of the rock and causes cave formation and characteristic stalactites and stalagmites and also forms hard water. Other important calcium compounds are nitrate, sulfide, chloride, carbide, cyanamide, and hypochlorite.

Scandium History

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Dmitri Mendeleev used his periodic law, in 1869, to predict the existence and some properties of three unknown elements including one he called ekaboron .

Lars Fredrick Nilson and his team, apparently unaware of that prediction in the spring of 1879, were looking for rare earth metals; using spectrum analysis he found a new element within the minerals euxenite and gadolinite. He named it Scandium, from the Latin Scandia meaning "Scandinavia", and by way of isolating the element he processed 10 kilograms of euxenite with other rare-earth residues, obtaining about 2 grams of very pure scandium oxide (Sc2O3).

Per Teodor Cleve concluded that scandium corresponded well to the hoped-for ekaboron, and notified Mendeleev of this in August.

Fischer, Brunger, and Grienelaus prepared metallic scandium for the first time in 1937, by electrolysis of a eutectic melt of potassium, lithium, and scandium chlorides at 700 to 800° C Tungsten wire in a pool of liquid zinc were the electrodes in a graphite crucible. The first pound of 99% pure scandium metal wasn't produced until 1960.

Potassium History

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Potassium was discovered in 1807 by Sir Humphrey Davy, who derived it from caustic potash (KOH). Potassium was the first metal that was isolated by electrolysis.

Potassium was not known in Roman times, and its names are not Classical Latin.
The name kalium was taken from the word "alkali", which came from Arabic al qalīy = "the calcined ashes".
The name potassium was made from the word "potash", which is English, and originally meant an alkali extracted in a pot from the ash of burnt wood or tree leaves.

Potassium makes up about 2.40% of the weight of the Earth's crust and is the seventh most abundant element in it. As it is very electropositive, potassium metal is difficult to obtain from its minerals.

Potassium salts such as carnallite, langbeinite, polyhalite, and sylvite are found in ancient lake and sea beds. These minerals form extensive deposits in these environments, making extracting potassium and its salts more economical. The principal source of potassium, potash, is mined in California, Germany, New Mexico, Utah, and in other places around the world. 3000 feet below the surface of Saskatchewan are large deposits of potash which are important sources of this element and its salts, with several large mines in operation since the 1960's. Saskatchewan pioneered the use of freezing of wet sands (the Blairmore formation) in order to drive mine shafts through them. See Potash Corporation of Saskatchewan. The oceans are another source of potassium, but the quantity present in a given volume of seawater is relatively low compared to sodium.

Potassium can be isolated through electrolysis of its hydroxide in a process that has changed little since Davy. Thermal methods also are employed in potassium production, using potassium chloride. Potassium is almost never found unbound in nature. However, in living organisms K+ ions are important in the physiology of excitable cells.

Argon History

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Argon (Greek argos meaning "inactive") was suspected to be present in air by Henry Cavendish in 1785 but was not discovered until 1894 by Lord Rayleigh and Sir William Ramsay.

This gas is isolated through liquid air fractionation since the atmosphere contains only 0.934% volume of argon (1.29% mass). The Martian atmosphere in contrast contains 1.6% of Ar-40 and 5 ppm Ar-36. In 2005, the Huygens probe also discovered the presence of Ar-40 on Titan, the largest moon of Saturn.

Before 1962, argon and the other noble gases were generally considered to be chemically inert and not able to form compounds. However, since then, scientists have been able to force the heavier noble gases to form compounds. In 2000, the first argon compounds were formed by researchers at the University of Helsinki. By shining ultraviolet light onto frozen argon containing a small amount of hydrogen fluoride, they were able to form argon hydrofluoride

Chlorine History

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Chlorine (Gr. χλωρος, greenish yellow) was discovered in 1774 by Carl Wilhelm Scheele, who mistakenly thought it contained oxygen. Chlorine was given its name in 1810 by Humphry Davy, who insisted that it was in fact an element.

Chlorine gas was first used as weapon against human beings in WWI on April 22nd, 1915.

In nature chlorine is found only as the chloride ion. Chlorides make up much of the salt dissolved in the Earth's oceans—about 1.9% of the mass of seawater is chloride ions. Even higher concentrations of chloride are dissolved in the Dead Sea and in underground brine deposits.

Most chlorides are soluble in water, so solid chlorides are usually only found in abundance in dry climates, or deep underground. Common chloride minerals include halite (sodium chloride), sylvite (potassium chloride), and carnallite (potassium magnesium chloride hexahydrate).

Industrially, elemental chlorine is usually produced by the electrolysis of sodium chloride dissolved in water.

Sulphur History

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Sulphur (Sanskrit, sulvere; Latin sulphur) was known in ancient times, and is referred to in the Biblical Pentateuch (Genesis). The word itself is almost certainly from the Arabic sufra meaning yellow, from the bright color of the naturally-occurring form.

English translations of the Bible commonly refer to sulphur as "brimstone", giving rise to the name of 'Fire and brimstone' sermons, which sinners are reminded of their fate of eternal damnation It is from this part of the Bible that hell is implied to "smell of sulphur", although as mentioned above sulphur in fact is odorless. The "smell of sulfur" usually refers to the odor of hydrogen sulfide, e.g. from rotten eggs. Burning sulphur, as may be anticipated in hell (rumor has it) gives sulphur dioxide, the smell associated with burnt matches.

Homer mentioned "pest-averting sulfur" in the 9th century BC and in 424 BC, the tribe of Boeotia destroyed the walls of a city by burning a mixture of coal, sulphur, and tar under them. Sometime in the 12th century, the Chinese invented gun powder which is a mixture of potassium nitrate (KNO3), carbon, and suphur. Early alchemists gave sulphur its own alchemical symbol which was a triangle at the top of a cross. In the late 1770s, Antoine Lavoisier helped convince the scientific community that sulphur was an element and not a compound. In 1867 sulphur was discovered in underground deposits in Louisiana and Texas. The overlying layer of earth was quicksand, prohibiting ordinary mining operations. Therefore the Frasch process was utilized.

Phosphorus History

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Phosphorus (Greek phosphoros, meaning "light bearer" which was the ancient name for the planet Venus) was discovered by German alchemist Hennig Brand in 1669 through a preparation from urine. Working in Hamburg, Brand attempted to distill salts by evaporating urine, and in the process produced a white material that glowed in the dark and burned brilliantly. Since that time, phosphorescence has been used to describe substances that shine in the dark without burning.

Early matches used white phosphorus in their composition, which was dangerous due to its toxicity. Murders, suicides and accidental poisonings resulted from its use (An apocryphal tale tells of a woman attempting to murder her husband with white phosphorus in his food, which was detected by the stew giving off luminous steam). In addition, exposure to the vapors gave match workers a necrosis of the bones of the jaw, the infamous "phossy-jaw." When red phosphorus was discovered, with its far lower flammability and toxicity, it was adopted as a safer alternative for match manufacture.

Due to its reactivity to air and many other oxygen containing substances, phosphorus is not found free in nature but it is widely distributed in many different minerals. Phosphate rock, which is partially made of apatite (an impure tri-calcium phosphate mineral) is an important commercial source of this element. Large deposits of apatite are in Russia, Morocco, Florida, Idaho, Tennessee, Utah, and elsewhere. There are however concerns over how long these phosphorus deposits will last. USA will deplete their deposits around 2035. China and Morocco have the largest known deposits today, but they too will eventually be depleted. During that depletion there could be a serious problem for the worlds food production since phosphorus is such an essential ingredient in fertilizers.

The white allotrope can be produced using several different methods. In one process, tri-calcium phosphate, which is derived from phosphate rock, is heated in an electric or fuel-fired furnace in the presence of carbon and silica. Elemental phosphorus is then liberated as a vapor and can be collected under phosphoric acid.

Silicon History

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Silicon (Latin silex, silicis meaning flint) was first identified by Antoine Lavoisier in 1787, and was later mistaken by Humphry Davy, in 1800, for a compound. In 1811 Gay Lussac and Thénard probably prepared impure amorphous silicon through the heating of potassium with silicon tetrafluoride. In 1824 Berzelius prepared amorphous silicon using approximately the same method of Lussac. Berzelius also purified the product by repeatedly washing it.

Because silicon is an important element in semiconductor and high-tech devices, the high-tech region of Silicon Valley, California, is named after this element.

Silicon is a principal component of aerolites which are a class of meteoroids and also of tektites which is a natural form of glass.

Measured by weight, silicon makes up 25.7% of the earth's crust and is the second most abundant element on Earth, after oxygen. Elemental silicon is not found in nature. It occurs most often as oxides and as silicates. Sand, amethyst, agate, quartz, rock crystal, flint, jasper, and opal are some of the forms in which the oxide appears. Granite, asbestos, feldspar, clay, hornblende, and mica are a few of the many silicate minerals.

Aluminium History

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The ancient Greeks and Romans used salts of this metal as dyeing mordants and as astringents for dressing wounds, and alum is still used as a styptic. Further Joseph Needham suggested finds in 1974 showed the ancient Chinese used aluminium. In 1761 Guyton de Morveau suggested calling the base alum 'alumine'. In 1808, Humphry Davy identified the existence of a metal base of alum, which he named (see Spelling section).

Friedrich Wöhler is generally credited with isolating aluminium (Latin alumen, alum) in 1827 by mixing anhydrous aluminium chloride with potassium. However, the metal had been produced for the first time two years earlier in an impure form by the Danish physicist and chemist Hans Christian Ørsted. Therefore almanacs and chemistry sites often list Øersted as the discoverer of aluminium.[2] Still it would further be P. Berthier who discovered aluminium in bauxite ore and successfully extracted it. The Frenchman Henri Saint-Claire Deville improved Wöhler's method in 1846 and described his improvements in a book in 1859, chief among these being the substitution of sodium for the considerably more expensive potassium.

The American Charles Martin Hall of Oberlin, OH applied for a patent (400655) in 1886 for an electrolytic process to extract aluminium using the same technique that was independently being developed by the Frenchman Paul Héroult in Europe. The invention of the Hall-Héroult process in 1886 made extracting aluminium from minerals cheaper, and is now the principal method in common use throughout the world. Upon approval of his patent in 1889, Hall, with the financial backing of Alfred E. Hunt of Pittsburgh, PA, started the Pittsburgh Reduction Company, renamed to Aluminum Company of America in 1907, later shortened to Alcoa.

The statue known as Eros in Piccadilly Circus London, was made in 1893 and is one of the first statues to be cast in aluminium.Aluminium was selected as the material to be used for the apex of the Washington Monument, at a time when one ounce cost twice the daily wages of a common worker in the project.

Germany became the world leader in aluminium production soon after Adolf Hitler seized power. By 1942, however, new hydroelectric power projects such as the Grand Coulee Dam gave the United States something Nazi Germany could not hope to compete with, namely the capability of producing enough aluminium to manufacture sixty thousand warplanes in four years.

Sodium History

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Sodium (English, soda) has long been recognized in compounds, but was not isolated until 1807 by Sir Humphry Davy through the electrolysis of caustic soda. In medieval Europe a compound of sodium with the Latin name of sodanum was used as a headache remedy. Sodium's symbol, Na, comes for the neo-Latin name for a common sodium compound named natrium, which comes from the Greek nítron, a kind of natural salt. As early as 1860 Kirchhoff and Bunsen noted the sensitivity that a flame test for sodium could have. Stating in Annalen der Physik und der Chemie in the paper "Chemical Analysis by Observation of Spectra": "In a corner of our 60 cu.m. room farthest away from the apparatus, we exploded 3 mg. of sodium chlorate with milk sugar while observing the nonluminous flame before the slit. After a few minutes, the flame gradually turned yellow and showed a strong sodium line that disappeared only after 10 minutes. From the weight of the sodium salt and the volume of air in the room, we easily calculate that one part by weight of air could not contain more than 1/20 millionth weight of sodium."

Neon History

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Neon (Greek neos meaning "new") was discovered by English chemists William Ramsay and Morris Travers in 1898.

Even though neon is for most practical purposes an inert element, it can form an exotic compound with fluorine in the laboratory. It is not known for certain if this or any neon compound exists naturally but some evidence suggests that this may be true.

Fluorine History

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Fluorine in the form of fluorspar (calcium fluoride) was described in 1529 by Georgius Agricola for its use as a flux, which is a substance that is used to promote the fusion of metals or minerals. In 1670 Schwandhard found that glass was etched when it was exposed to fluorspar that was treated with acid. Karl Scheele and many later researchers, including Humphry Davy, Gay-Lussac, Antoine Lavoisier, and Louis Thenard all would experiment with hydrofluoric acid, easily obtained by treating calcium fluoride (fluorspar) with concentrated sulfuric acid.

It was eventually realized that hydrofluoric acid contained a previously unknown element. This element was not isolated for many years after this due to its extreme reactivity - it is separated from its compounds only with difficulty and then it immediately attacks the remaining materials of the compound. Finally in 1886 fluorine was isolated by Henri Moissan after almost 74 years of continuous effort. It was an effort which cost several researchers their health or even their lives, and for Moissan, it earned him the 1906 Nobel Prize in chemistry.

The first large scale production of fluorine was needed for the atomic bomb Manhattan project in World War II where the compound uranium hexafluoride (UF6) was used to separate the 235U and 238U isotopes of uranium. Today both the gaseous diffusion process and the gas centrifuge process use gaseous (UF6) to produce enriched uranium for nuclear power applications.

The derivation of elemental fluorine from hydrofluoric acid is exceptionally dangerous, killing or blinding several scientists who attempted early experiments on this halogen. These men came to be referred to as "Fluorine Martyrs."

Oxygen History

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Oxygen was first discovered by Michał Sędziwój, Polish alchemist and philosopher in late 16th century. Sędziwój assumed the existence of oxygen by warming nitre (saltpeter). He thought of the gas given off as "the elixir of life".

Oxygen was again discovered by the Swedish pharmacist Carl Wilhelm Scheele sometime before 1773, but the discovery was not published until after the independent discovery by Joseph Priestley on August 1, 1774, who called the gas dephlogisticated air (see phlogiston theory). Priestley published his discoveries in 1775 and Scheele in 1777; consequently Priestley is usually given the credit. It was named by Antoine Laurent Lavoisier after Priestley's publication in 1775.

Nitrogen History

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Nitrogen (Latin nitrum, Greek Nitron meaning "native soda", "genes", "forming") is formally considered to have been discovered by Daniel Rutherford in 1772, who called it noxious air or fixed air. That there was a fraction of air that did not support combustion was well known to the late 18th century chemist. Nitrogen was also studied at about the same time by Carl Wilhelm Scheele, Henry Cavendish, and Joseph Priestley, who referred to it as burnt air or phlogisticated air. Nitrogen gas was inert enough that Antoine Lavoisier referred to it as azote, from the Greek word αζωτος meaning "lifeless". This term has become the French word for "nitrogen" and later spread out to many other languages.

Compounds of nitrogen were known in the Middle Ages. The alchemists knew nitric acid as aqua fortis. The mixture of nitric and hydrochloric acids was known as aqua regia, celebrated for its ability to dissolve gold. The earliest industrial and agricultural applications of nitrogen compounds used it in the form of saltpeter (sodium- or potassium nitrate), notably in gunpowder, and much later, as fertilizer, and later still, as a chemical feedstock.

Cabon History

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Carbon was discovered in prehistory and was known to the ancients, who manufactured it by burning organic material in insufficient oxygen (making charcoal). Diamonds have long been considered rare and beautiful. One of the last-known allotropes of carbon, fullerenes, were discovered as byproducts of molecular beam experiments in the 1980s.

The name comes from French charbone, which in turn came from Latin carbo, meaning charcoal. In German and Dutch, the names for carbon are Kohlenstoff and koolstof respectively, both literally meaning "coal-stuff".

Magnesium History

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The name originates from the Greek word for a district in Thessaly called Magnesia. Joseph Black in England recognized magnesium as being an element in 1755, Sir Humphry Davy electrolytically isolated pure magnesium metal in 1808 from a mix of magnesia and HgO, and A. A. B. Bussy prepared it in coherent form in 1831. Magnesium is the eighth most abundant element in the earth's crust. It is an alkaline earth metal and therefore does not occur uncombined with other elements. It is found in large deposits of magnesite, dolomite, and other minerals.

Boron History

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Compounds of boron (Arabic Buraq from Persian Burah) have been known of for thousands of years. In early Egypt, mummification depended upon an ore known as natron, which contained borates as well as some other common salts. Borax glazes were used in China from 300 AD, and boron compounds were used in glassmaking in ancient Rome.

The element was not isolated until 1808 by Sir Humphry Davy, Joseph Louis Gay-Lussac, and Louis Jacques Thénard, to about 50 percent purity. These men did not recognize the substance as an element. It was Jöns Jakob Berzelius in 1824 who identified boron as an element. The first pure boron was produced by the American chemist W. Weintraub in 1909.

Beryllium History

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The name beryllium comes from the Greek beryllos, beryl. At one time beryllium was referred to as glucinium (from Greek glykys, sweet), due to the sweet taste of its salts. This element was discovered by Louis Vauquelin in 1798 as the oxide in beryl and in emeralds. Friedrich Wöhler and A. A. Bussy independently isolated the metal in 1828 by reacting potassium and beryllium chloride.

Lithuim History

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Petalite, which contains lithium, was first discovered by the Brazilian scientist José Bonifácio de Andrada e Silva toward the end of the 1700s on a trip to Sweden. Lithium was discovered by Johann Arfvedson in 1817. Arfvedson found the new element within the minerals spodumene and lepidolite in a petalite ore, LiAl(Si2O5)2, he was analyzing during a routine investigation of some minerals from a mine on the island Utö in Sweden. In 1818 Christian Gmelin was the first to observe that lithium salts give a bright red color in flame. Both men tried and failed to isolate the element from its salts.

The element was not isolated until William Thomas Brande and Sir Humphrey Davy later used electrolysis on lithium oxide in 1818. Bunsen and Matiessen isolated larger quantities of the metal by electrolysis of lithium chloride in 1855. Commercial production of lithium metal was achieved in 1923 by the German company Metallgesellschaft through using electrolysis of molten lithium chloride and potassium chloride. It was apparently given the name "lithium" (Greek λιθοσ (lithos), meaning "stone") because it was discovered from a mineral while other common alkali metals were first discovered from plant tissue.

Helium history

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Helium was first detected on August 18, 1868 as a bright yellow line with a wavelength of 587.49 nm in the spectrum of the chromosphere of the Sun, by French astronomer Pierre Janssen during a total solar eclipse in India. Janssen was at first ridiculed since no element had ever been detected in space before being found on EngEarth. October 20th the same year,english astronomer Norman Lockyer also observed the same yellow line in the solar spectrum and concluded that it was caused by an unknown element after unsuccessfully testing to see if it were some new type of hydrogen. Since it was near the Fraunhofer D line he later named the new line D3, distinguishing it from the nearby D1 and D2 double lines of sodium. He and English chemist Edward Frankland named the element after the Greek word for the Sun god, Helios, and, assuming it was a metal, gave it an -ium ending (a mistake that was never corrected).

British chemist William Ramsay isolated helium on March 26, 1895 by treating cleveite (now known to be uraninite) with mineral acids. Ramsay was looking for argon but noticed the yellow D3 line after he removed nitrogen and oxygen from the gas liberated by the sulfuric acid he put on the cleveite sample. These samples were identified as helium by Lockyer and British physicist William Crookes. It was independently isolated from cleveite the same year by Swedish chemists Per Teodor Cleve and Abraham Langlet in Uppsala in Sweden. They collected enough of the gas to accurately determine its atomic weight.

An oil drilling operation in Dexter, Kansas created a gas geyser in 1903 that contained 12% by volume of an unidentified gas. American chemists Hamilton Cady and David McFarland of the University of Kansas discovered it was helium and published a paper in 1907 saying that helium could be extracted from natural gas. Also in 1907, Ernest Rutherford and Thomas Royds demonstrated that an alpha particle is a helium nucleus.

Helium was first liquefied by Dutch physicist Heike Kamerlingh Onnes in 1908 in Leiden by cooling the gas to less than one kelvin. He tried to solidify it by reducing the temperature to 0.8 K but failed because helium does not have a triple point temperature where the solid, liquid and gas phases are at equilibrium. It was first solidified in 1926 by his student Willem Hendrik Keesom who subjected helium to a similar amount of cooling as Kamerlingh Onnes but at 25 standard atmospheres of pressure.

In 1938, Russian physicist Pyotr Leonidovich Kapitsa discovered that liquid helium-4 has almost no viscosity at temperatures near absolute zero, a phenomenon now called superfluidity. In 1972, the same phenomenon was observed in liquid helium-3 by American physicists Douglas D. Osheroff, David M. Lee, and Robert C. Richardson.

Hydrogen History

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Hydrogen was first produced by Theophratus Bombastus von Hohenheim (1493–1541)—also known as Paracelsus—by mixing metals with acids. He was unaware that the explosive gas produced by this chemical reaction was hydrogen. In 1671, Robert Boyle described the reaction between two iron fillings and dilute acids, which results in the production of gaseous hydrogen.[3] In 1766, Henry Cavendish was the first to recognize hydrogen as a discrete substance, by identifying the gas from this reaction as "inflammable" and finding that the gas produces water when burned in air. Cavendish stumbled on hydrogen when experimenting with acids and mercury. Although he wrongly assumed that hydrogen was a compound of mercury—and not of the acid—he was still able to accurately describe several key properties of hydrogen.

Antoine Lavoisier gave the element its name and proved that water is composed of hydrogen and oxygen. One of the first uses of the element was for balloons. The hydrogen was obtained by mixing sulfuric acid and iron. In 1931, Harold C. Urey discovered deuterium, an isotope of hydrogen, by repeated distilling the same sample of water. For this discovery, Urey received the Nobel Prize in Chemistry in 1934. In the same year, the third isotope, tritium, was discovered. Because of its relatively simple structure, hydrogen has often been used in models of how an atom works.